Calculate the rotational partition function of H 2 O at 298 K from its rotational constants 27.878

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Calculate the rotational partition function of H2O at 298 K from its rotational constants 27.878 cm−1, 14.509 cm−1, and 9.287 cm−1. Above what temperature is the high-temperature approximation valid to within 10 per cent of the true value?

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Physical Chemistry

ISBN: 9780716787594

8th Edition

Authors: Peter Atkins, Julio De Paula

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