First-order decay processes as described in the previous problem can also be applied to a variety of

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First-order decay processes as described in the previous problem can also be applied to a variety of atomic and molecular processes. For example, in aqueous solution the decay of singlet molecular oxygen (O2(1Δg)) to the ground-state triplet configuration proceeds according to:

[0,('4,)] -(2.4x10' s-1)r

In the above expression, 1 [O2 (1Δg)] is the concentration of singlet oxygen at a given time, and the subscript €œ0€ indicates that this is the concentration of singlet oxygen present at the beginning of the decay process (t = 0).

a. How long does one have to wait until 90% of the singlet oxygen has decayed?

b. How much singlet oxygen remains after t = (2.4 × 105 sˆ’1)ˆ’1?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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