Question: In constructing the vibrational partition function, we found that the definition depended on whether zero-point energy was included in the description of the energy levels.

In constructing the vibrational partition function, we found that the definition depended on whether zero-point energy was included in the description of the energy levels. However, the expression for the probability of occupying a specific vibrational energy level was independent of zero-point energy. Why?

Step by Step Solution

★★★★★

3.46 Rating (169 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

The zeropoint energy can be thought of as a consta... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Students Have Also Explored These Related Physical Chemistry Questions!

Evaluate the vibrational partition function for SO 2 at 298 K, where the vibrational frequencies are 519, 1151, and 1361cm 1 .

Evaluate the vibrational partition function for H 2 O at 2000 K, where the vibrational frequencies are 1615, 3694, and 3802 cm 1 .

Evaluate the vibrational partition function for CFCl 3 at 298 K, where the vibrational frequencies are (with degeneracy in parentheses) 1081, 847 (2), 535, 394 (2), 350., and 241(2) cm 1 .

This section will require you to CHOOSE ONE question to answer from a selection of 4 questions which require an extended response from you. ? You may be asked to choose from questions regarding any...

a. In this chapter, the assumption was made that the harmonic oscillator model is valid such that anharmonicity can be neglected. However, anharmonicity can be included in the expression for...

. Required: Critiques Overview please do it Top management commitment Top management commitment, corporate social responsibility and green human resource management A Malaysian study 2051 Received 17...

1. In 2013, several data server companies took a dramatic decision to begin using energy surcharges to recapture rising energy costs. However, customers are critical of how the energy surcharges are...

Guidelines for the Methods and Results paper Below are the step-by-step instructions for completing the paper due in Lesson 12. Follow these steps, and use the knowledge you've gained this semester...

Explain how the principles of quantum mechanics are able address the issues. The development of quantum mechanical theory stems from several issues that could not be addressed by the principles of...

Castalia Co. has net income (500K), preferred dividends declared ($100K), and common shares outstanding (230K). What is the companys EPS, to the nearest penny? Castalia Co. has the following:...

Measuring the amount of myelin basic protein (MBP) in the CSF can be used to monitor the course of: a. Hemorrhage b. Multiple sclerosis C. All answers are correct d. Meningitis

Sam's Snakes, Inc., an S Corporation, has had E&P from when it was a C Corporation on the last day of each of the last 3 tax years. Over those same 3 tax years, passive investment income (PII) was...

7. If the government of Mexico introduces an import quota of 4 million cars a year, what will be the price of a car in Mexico, the quantity of cars produced in Mexico, and the quantity imported?

By what percentage does the radius of gyration of a one-dimensional polymer chain increase (+) or decrease () when the bond angle between units is limited to 109? What is the percentage change in...

Use the following information and the expression for R g of a solid sphere quoted in the text (following eqn 17A.6), to classify the given species as globular or rod-like. Data in eqn 17A.6 Serum...

Derive expressions for the moments of inertia and hence the radii of gyration of (a) A uniform thin disk, (b) A long uniform rod, (c) A uniform sphere.

Q4 1 Point Divine is a company with no debt in the capital structure. Its overall cost of capital is 9%. The firm is considering a new capital structure with 50% debt. The interest rate on the debt...

Over and Under, Inc. manufactures weaving looms. Before the period began, the company prepared the following manufacturing overhead budget for an expected activity level of 15,000 direct labor hours...

V Espanol The Cadet is a popular model of sport utility vehicle, known for its relatively high resale value. The bivariate data given below were taken from a sample of sixteen Cadets, each bought new...