Pure rotational Raman spectra of gaseous C 6 H 6 and C 6 D 6 yield the
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Pure rotational Raman spectra of gaseous C6H6 and C6D6 yield the following rotational constants: B(C6H6) = 0.189 60 cm−1, B(C6D6) = 0.156 81 cm−1. The moments of inertia of the molecules about any axis perpendicular to the C6 axis were calculated from these data as I(C6H6) = 1.4759 × 10−45 kg m2, I(C6D6) = 1.7845 × 10−45 kg m2. Calculate the CC, CH, and CD bond lengths.
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