Suppose that the internuclear distance may be written R=R e +x where R e is the equilibrium
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Suppose that the internuclear distance may be written R=Re+x where Re is the equilibrium bond length. Also suppose that the potential well is symmetrical and confines the oscillator to small displacements. Deduce expressions for 1/〈R〉2, 1/〈R2〉, and 〈1/R2〉 to the lowest non-zero power of 〈x2〉/Re2 and confirm that values are not the same.
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The internuclear distance may be written RRex where Re is the equilibrium bond length Also ...View the full answer
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Related Book For
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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