The Edison storage cell is described by Fe(s) FeO(s) KOH(aq, a KOH ) Ni 2 O 3

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The Edison storage cell is described by

Fe(s) FeO(s) KOH(aq, aKOH) Ni2O3(s) NiO(s) Ni(s)

and the half-cell reactions are as follows:

Ni2O3(s) + H2O(l) + 2e → 2NiO(s) + 2OH (aq)......................Eo = 0.40 V

FeO(s) + H2O(l) + 2e → Fe(s) + 2OH (aq)..............................Eo = −0.87 V

a. What is the overall cell reaction?

b. How does the cell potential depend on the activity of the KOH?

c. How much electrical work can be obtained per kilogram of the active materials in the cell?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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