Question: Use the accurate expression for the rotational partition function calculated in Problem 15B.6 for HCl(g) to calculate the rotational contribution to the molar entropy over
Use the accurate expression for the rotational partition function calculated in Problem 15B.6 for HCl(g) to calculate the rotational contribution to the molar entropy over a range of temperature and plot the contribution as a function of temperature.
Data in Problem 15B.6
The pure rotational microwave spectrum of HCl has absorption lines at the following wavenumbers (incm−1): 21.19, 42.37, 63.56, 84.75, 105.93, 127.12, 148.31, 169.49, 190.68, 211.87, 233.06, 254.24, 275.43, 296.62, 317.80, 338.99, 360.18, 381.36, 402.55, 423.74, 444.92, 466.11, 487.30, 508.48. Calculate the rotational partition function at 25 °C by direct summation.
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