Consider the titration of 25.0 mL of 0.010 0 M Sn 2+ by 0.050 0 M Tl

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Consider the titration of 25.0 mL of 0.010 0 M Sn2+ by 0.050 0 M Tl3+ in 1 M HCl, using Pt and saturated calomel electrodes to find the end point.
(a) Write a balanced titration reaction.
(b) Write two different half-reactions for the indicator electrode.
(c) Write two different Nernst equations for the cell voltage.
(d) Calculate E at the following volumes of Tl3+: 1.00, 2.50, 4.90, 5.00, 5.10, and 10.0 mL. Sketch the titration curve.

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