Consider the titration of 25.0 mL of 0.050 0 M Sn 2+ with 0.100 M Fe 3+

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Consider the titration of 25.0 mL of 0.050 0 M Sn2+ with 0.100 M Fe3+ in 1 M HCl to give Fe2+ and Sn4+, using Pt and calomel electrodes.

(a) Write a balanced titration reaction.

(b) Write two half-reactions for the indicator electrode.

(c) Write two Nernst equations for the cell voltage.

(d) Calculate E at the following volumes of Fe3+: 1.0, 12.5, 24.0, 25.0, 26.0, and 30.0 mL. Sketch the titration curve.

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