Consider synthesis of poly(ethylene terephthalate) by polyesterification. Rate constants for polyesterification are 10^-2 (L mol^-1)2 s^-1 (no
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Consider synthesis of poly(ethylene terephthalate) by polyesterification. Rate constants for polyesterification are 10^-2 (L mol^-1)2 s^-1 (no catalyst added) and 2x10^-2 L mol^-1s^-1 (catalyst added).
A) How long would it take to prepare a polyester of weight average molecular weight 3,000 under each set of conditions? Given that the initial dicarbixilic acid concentration is 3 mol L^-1.
B)If 5 mol% excess of diol were to be used in the previous problem, what number average molecular weight would be obtained if the reactions were carried to the same conversion?
Related Book For
Probability and Random Processes With Applications to Signal Processing and Communications
ISBN: 978-0123869814
2nd edition
Authors: Scott Miller, Donald Childers
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