Question: 1 0 . 2 - 1 6 Based on vapor - liquid equilibrium data, some authors have claimed that the benzene ( 1 ) -

10.2-16 Based on vapor-liquid equilibrium data, some authors have claimed that the benzene (1)- cyclohexane (2) mixture is described by Ge*= A.x112 where A (J/mol)=3750-8T for T in degrees K. a. Derive expressions for the activity coefficients of benzene and cyclohexane. b. Determine the enthalpy and entropy changes on mixing when I mole ofPG18 benzene and 2 moles of .cyclohexane are mixed at T =300 K and con- stant pressure. c. Given the following vapor pressure data at T =320 K, P P =0.3203 bar and PCP =0.3218 bar, determine the bubble pressure of the liquid in part (b) at T =320 K, and the com- position of the vapor in equilibrium with that liquid. s or o as

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