Question: ( 1 8 % ) ( a ) For a real gas obeying the virial equation of state, P V R T = Z =

(18%)(a) For a real gas obeying the virial equation of state, PVRT=Z=1+BP+CP2+DP3+dots, prove that ln(fP)|P|=P=P=0P=PZ-1PdP(f: fugacity).
(b) The change of Gibbs free energy for 1 mole of pure i
(condensed phase) to 1 mole of i in a sulution is bar(G)iM. Explain why bar(G)iM=RTlnai and give the definition of ai.(c) For a A-B binary system, draw the "GMvs,xB" plot and explain why
bar(G)BM=GM+xAdGMdxB
 (18%)(a) For a real gas obeying the virial equation of state,

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