1. The following table is a fragmentation table fora simple compound. Use the table in Moodle to identify the fomula of any fragments that you can. Mark these fomulae in the space next to the mass number in the chart. Use the evidence from the fragments to sketch the molecule. (5 marks) 14.015650 30.042479 45.053377 15.019004 30.046950 45.057868 15.023475 31.037727 45.065954 16.026829 31.042198 46.061202 16.031300 31.050304 57.057858 17.034654 32.045552 58.061202 27.023475 42.034373 58.065673 28.018723 42.046950 59.069027 28.026829 43.037727 59.073598 28.031300 43.042198 60.076852 29.022077 43.050304 72.081353 29.026548 43.054775 73.084677 29.034654 44.045552 73.089148 29.039125 44.050083 74.092502 30.029902 44.058129 30.034373 44.062600 FM FM FM FM 32.0375 32.0262 46.0419 12.0000 13.0078 32.9976 33.0215 47.0007 47.0133 47.0371 59.0246 59.0484 59.0133 59.0371 59.0610 59.0497 59.0736 14.0031 14.0157 34.0054 15.0109 15.0235 38.0157 47.9847 48.0085 48.0324 48.0211 39.0109 39.0235 49.0164 15.9949 16.0187 16.0313 60.0085 60.0324 60.0563 60.0211 60.0450 60.0688 60.0575 60.0000 40.0187 40.0313 52.0313 17.0027 17.0266 53.0266 53.0391 41.0140 41.0266 41.0391 18.0106 61.0164 61.0402 61.0641 61.0289 61.0528 54.0218 54.0106 54.0344 54.0470 24.0000 26.0031 26.0157 12 13 CH 14 N CH, 15 HN CH, 16 0 HN CH 17 HO HEN 18 HO 24 26 CN CH 27 CHN CH, 28 N. CO CH_N CH 29 HN, CHO CHUN CH, 30 NO HN CHO CH.N CH 31 HNO HN CH,O CH, 32 02 H.NO H.NZ CHO 33 , H.NO 34 HO 38 CH 39 CHN CH, 40 CHN , 41 CHN CHN CH, 42 N CNO CHAN, CHO CHN CH 43 HN, CHNO CH,N2 CHO CHEN CH 44 NO CO2 CH NO CH.NL CH,0 CHN CH 45 CH.NO CHEN, CHO CHN 46 NOZ CH,02 CH.NO CH.N 42.0093 41.9980 42.0218 42.0106 42.0344 42.0470 27.0109 27.0235 CH,0 47 , CHO, CH,NO 48 O H.NO, H.NO CHO, 49 H.NO 52 CH 53 CHEN CH 54 CHN CHO CH.N CH 55 CH,N ,0 CHEN CH, 56 CO2 CH NO CH.N CHO CHN , 57 CHNO CHEN, CHO CHAN CH, 58 CH,NO CHNG CHO CH.NO CH.NL CHO CHN CHO 59 CHNO 55.0297 55.0184 55.0422 55.0548 CH,NO CHEN, CHO, CH NO CH,N, CHO CH,N 60 CH.NO, CH.NO CH,N CH,02 CH.NO CH, CHO C 61 CH.NO, CH_NO CH,N, CHO, CH,NO 62 CH,0, CH.NO, CH.NO CHO 63 HNO CH NO, 64 CH 65 CH,N CH 66 CHN CH 67 CH,N CH,0 CHEN CH, 68 CH.NZ CHO CHN CH 69 CH,NO CHEN, 62.0003 62.0242 62.0480 62.0368 28.0062 27.9949 28.0187 28.0313 62.9956 63.0320 43.0170 43.0058 43.0297 43.0184 43.0422 43.0548 55.9898 56.0136 56.0375 56.0262 56.0501 56.0626 64.0313 65.0266 65.0391 29.0140 29.0027 29.0266 29.0391 44.0011 43.9898 44.0136 44.0375 44.0262 44.0501 44.0626 57.0215 57.0453 57.0340 57.0579 57.0705 66.0344 66.0470 29.9980 30.0218 30.0106 30.0344 30.0470 67.0297 67.0184 67.0422 67.0548 31.0058 31.0297 31.0184 31.0422 45.0215 45.0453 45.0340 45.0579 58.0167 58.0406 58.0054 58.0293 58.0532 58.0419 58.0657 58.0783 68.0375 68.0262 68.0501 68.0626 31.9898 32.0136 45.9929 46.0054 46.0293 46.0532 59.0007 69.0215 69.0453 FM FM FM FM 69.0340 69.0579 69.0705 76.0399 76.0637 76.0524 76.0187 76.0313 85.0767 85.0653 85.0892 85.1018 90.0555 90.0794 90.0681 90.0470 77.0113 77.0238 77.0477 77.0391 70.0406 70.0054 70.0293 70.0532 70.0419 70.0657 70.0783 71.0246 71.0484 71.0133 71.0371 71.0610 71.0497 71.0736 71.0861 86.0116 86.0355 86.0594 86.0242 86.0480 86.0719 86.0368 86.0606 86.0845 86.0732 86.0970 86.1096 91.0031 91.0269 91.0508 91.0746 91.0395 91.0634 91.0422 91.0548 78.0317 78.0344 78.0470 79.0422 79.0548 92.0109 92.0348 92.0586 92.0473 92.0262 92.0501 92.0626 80.0249 80.0375 80.0262 80.0501 80.0626 CHO CHAN CH, 70 CHN C,H,O, CH.NO CHEN CH,0 CH N CH 71 CH.NO CHEN, CHO CH.NO CH,N, CHO C.HN CSH, 72 CH NO CH.NO CHEN, CHO, CHNO CH,N CHO CHN C3H12 73 CH,NO, CH NO CH,N, CHO, CH,NO CH.NZ C,H,O C,H,N 74 CHO CH.NO, CH.NO CH,N C,H,O, CH.NO CHON CHO 75 CH,0 CH.NO, CH,NO CH,N, 72.0085 72.0324 72.0563 72.0211 72.0449 72.0688 72.0575 72.0814 72.0939 CH.NO CH.NO C,H,O, CH_N CH 77 CH,NO, CHO, CH,NO , 78 CHO, CHN CH 79 CHEN CH 80 CHNG CH.NL CHO CH N CH, 81 CHEN, CHEN, CH,0 CH,N CH, 82 CHN C.H.NO CH.NL CHO CHN CH. 83 CHEN, CH,02 CHNO CHUNG CHO CH.N CH 84 CH,N, CHO, CH.NO CH,N CH,O CHN CH2 85 CH.N CHO CHN CH 86 CH,N,P, CH.NO CHEN CH.NO, CH.NO CHEN, C,H,O, C.H.NO CHN CH,00 CHN CH4 87 CH, C,H,O, CH,NO, CH.NO C,HN, C,H,O, CH.NO CH, N2 C,H,O C,HN 88 CH.NO, CHNO CH.N C,H,O, CH.NO CH.NO CHN, C,H,O, C.H.NO C.HN, CHO 89 CH,NO, CH,NO CHN, CHO, CH.NO, CH.NO CH, N, C,H,O2 CH, NO CH, 90 CH.NO, HN 87.0672 87.0082 87.0320 87.0559 87.0798 87.0446 87.0684 87.0923 87.0810 87.1049 81.0328 81.0453 81.0340 81.0579 81.0705 CH.NO, CHNO CHO, CH 91 CHO, CH.NO, CH.NO CH.NO CHO, CH.NO, CHEN CH, 92 CHO CH.NO, CCHN 0, CHO, CHO CH.N CH 93 CHO, CH,NO, C,H,N2 CHO CH,N CH, 94 CHO. CHN CH.NO CH.NZ CH,0 CHN CHO 95 CHEN, CH NO CHUNG C,H,O CHN CH 96 C,HN, CHO, CH.NO CH,N CHO CHN CH2 97 C,H,N, CH.NO 93.0187 92.0426 93.0453 93.0340 93.0579 93.0705 73.0164 73.0402 73.0641 73.0289 73.0528 73.0767 73.0653 73.0892 82.0406 82.0293 82.0532 82.0419 82.0657 82.0783 88.0273 88.0511 88.0750 88.0160 88.0399 88.0637 88.0876 88.0524 88.0763 88.1001 88.0888 94.0266 94.0406 94.0293 94.0532 94.0419 94.0657 94.0783 83.0484 83.0133 83.0371 83.0610 83.0497 83.0736 83.0861 95.0484 95.0371 95.0610 95.0497 95.0736 95.0861 74.0003 74.0242 74.0480 74.0719 74.0368 74.0606 74.0845 74.0732 84.0563 84.0211 84.0449 84.0688 84.0575 84.0814 84.0939 89.0351 89.0590 89.0829 89.0238 89.0477 89.0715 89.0954 89.0603 89.0841 89.0391 96.0563 96.0211 96.0449 96.0688 96.0575 96.0814 96.0939 75.0082 75.0320 75.0559 75,0798 90.0191 000429 97.0515 97.0402 CIN 95402