Question: 2. In class we solved the quantum harmonic oscillator problem for a diatomic molecule. As part of that solution we transformed coordinates from x, the

 2. In class we solved the quantum harmonic oscillator problem fora diatomic molecule. As part of that solution we transformed coordinates from

2. In class we solved the quantum harmonic oscillator problem for a diatomic molecule. As part of that solution we transformed coordinates from x, the oscillator displacement coordinate, to the unitless y using the relationship y = */a 1/4 = uk where u is the reduced mass of the diatomic molecule and k is the force constant. The solution turned out to be: Wv y) = Ny Hyby) e -1/2 where Ny is a normalization constant, Hv(y) are the Hermite polynomials and v is the quantum number with values of v=0, 1, 2, 3... The first four wave functions are: 1/2 W.(y) = lan / -Y* 12 e 1 16y) = 1/2 (2ye 6-7/ 2an 1 1/2 42(y) = 8an"/2) (4y2 2) e-/2 1 1/2 23(y) = (8y3 12y) e 2/2 (36an 1/2 where the first bracketed term is Ny, the second term Hy(y), and e 6-7/ assures correct behavior of y(y) as y to. We now introduce the following operators: Annihilation operator (y + b ) (y - ) Creation operator where these names will soon be apparent. We now introduce the following operators: (y + m ) Annihilation operator (y - y) Creation operator where these names will soon be apparent. a. Determine the commutator of the two operators. Can they have simultaneous eigenfunctions? b. Apply (y + ) to Yo, 41, 42, and 3. Write each answer in terms of one of the wavefunctions times a constant. c. Do the same for (v - ) as in part b. but only for 40, 41, and 42- d. Now write your results in the form (v + ) *v(y) = f(vwv) .s#v a 4v) fv)(y (v - ) *v%) = f'(W)#v" () ) y for each of the operations, where f (v) and f'(v) are v containing constants and v' and v" are the values of v found for the resultant wavefunctions. e. Now write the general results by identifying f'(v), f'(v), v' and v". (+)) = (v - ay) 400) = Wvy

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