The decomposition rate of dimethyl ether (CH3OCH3) in the gas phase was studied by Hinshelwood (1927) by
Question:
The decomposition rate of dimethyl ether (CH3OCH3) in the gas phase was studied by Hinshelwood (1927) by measuring the increases in pressure that accompany decomposition in a constant volume batch reactor at a given temperature. The reaction is complicated since formaldehyde appears as an intermediate product, but assume that the reaction is complete in the following sense CH_3 OCH_3 → CH_4 + H_2 + CO In an experiment at 504 ° C in which it was 41.6 kPa, the following values of the pressure change were obtained
t (s) | k Pa | t (s) | k Pa |
0 | 0 | 916 | 26.7 |
207 | 7.5 | 1195 | 33.3 |
3390 | 12.8 | 1587 | 41.6 |
481 | 15.5 | 2240 | 53.6 |
665 | 20.8 | 2660 | 58..3 |
777 | 23.5 | 3155 | 62.3 |
82.5 |
Test the hypothesis that the reaction is of the first order with respect to the ether
Elementary Principles of Chemical Processes
ISBN: 978-0471720638
3rd Edition
Authors: Richard M. Felder, Ronald W. Rousseau