3. (30)a) Show that T.dS= cv.dT+(Ta/B).dV using generalized method. dS=cp/T.dT-a.V.dP and dV=aV.dT-BV.dP b) Calculate the entropy...

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3. (30)a) Show that T.dS= cv.dT+(Ta/B).dV using generalized method. dS=cp/T.dT-a.V.dP and dV=aV.dT-BV.dP b) Calculate the entropy change as the temperature and volume of the one mole of ideal gas were taken from 273K and 22.4lts to 373K and 44.8 Its. R-8.314 J/mol.K-0.082 lt.atm/mol.K 3. (30)a) Show that T.dS= cv.dT+(Ta/B).dV using generalized method. dS=cp/T.dT-a.V.dP and dV=aV.dT-BV.dP b) Calculate the entropy change as the temperature and volume of the one mole of ideal gas were taken from 273K and 22.4lts to 373K and 44.8 Its. R-8.314 J/mol.K-0.082 lt.atm/mol.K