Prepare a schematic Brouwer diagram for NiO indicating: (i) (ii) the intrinsic defects under ambient conditions....

 

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Prepare a schematic Brouwer diagram for NiO indicating: (i) (ii) the intrinsic defects under ambient conditions. the intrinsic defects under reducing conditions. (iii) the intrinsic defects under oxidizing conditions. (iv) (v) (vi) Explain where the values of the slopes come from in each region. Explain why the equilibrium constants (log K1/2 and K₁) are where they are. Why is there a difference between [e] and [V."] in the reducing region of the Brouwer diagram? (vii) Why is there a difference between [h*] and [VNi" ] in the oxidizing region of the Brouwer diagram? Prepare a schematic Brouwer diagram for NiO indicating: (i) (ii) the intrinsic defects under ambient conditions. the intrinsic defects under reducing conditions. (iii) the intrinsic defects under oxidizing conditions. (iv) (v) (vi) Explain where the values of the slopes come from in each region. Explain why the equilibrium constants (log K1/2 and K₁) are where they are. Why is there a difference between [e] and [V."] in the reducing region of the Brouwer diagram? (vii) Why is there a difference between [h*] and [VNi" ] in the oxidizing region of the Brouwer diagram?