5.4A For the catalytic cycle Cl+03 CIO+ O k = 2.9 x 10- exp(-260/T) CIO+O CI+...

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5.4A For the catalytic cycle Cl+03¹ CIO+ O₂ k₁ = 2.9 x 10-¹¹ exp(-260/T) CIO+O² CI+ O₂ k₂= 3.0 x 10-11 exp(70/T) determine the ratio of [CIO]/[03] at which the rate of ozone destruction from this cycle equals that from the Chapman cycle at 20 km, where T220 K. If the O3 mixing ratio is 4ppm, what concentration of CIO does this correspond to? 5.4A For the catalytic cycle Cl+03¹ CIO+ O₂ k₁ = 2.9 x 10-¹¹ exp(-260/T) CIO+O² CI+ O₂ k₂= 3.0 x 10-11 exp(70/T) determine the ratio of [CIO]/[03] at which the rate of ozone destruction from this cycle equals that from the Chapman cycle at 20 km, where T220 K. If the O3 mixing ratio is 4ppm, what concentration of CIO does this correspond to?