Question: 9 . 2 6 . Ethylene oxide is produced by the catalytic oxidation of ethylene: C 2 H 4 ( g ) + 1 2

9.26. Ethylene oxide is produced by the catalytic oxidation of ethylene:
C2H4(g)+12O2(g)longrightarrowC2H4O(g)
An undesired competing reaction is the combustion of ethylene to CO2.
The feed to a reactor contains 2molC2H4molO2. The conversion and yield in the reactor
are respectively 25% and 0.70molC2H4O produced/mol C2H4 consumed. A multiple-unit process
separates the reactor outlet stream components: C2H4 and O2 are recycled to the reactor, C2H4O
is sold, and CO2 and H2O are discarded. The reactor inlet and outlet streams are each at 450C,
and the fresh feed and all species leaving the separation process are at 25C. The combined fresh
feed-recycle stream is preheated to 450C.
(a) Taking a basis of 2mol of ethylene entering the reactor, draw and label a flowchart of the com-
plete process (show the separation process as a single unit) and calculate the molar amounts and
compositions of all process streams.
(b) Calculate the heat requirement (kJ) for the entire process and that for the reactor alone.
Data for C2H4O(g)?
hat(H)f=-51.00kJmol
Cp[Jmol*K]=-4.69+0.2061T-9.99510-5T2
where T is in kelvin.
(c) Calculate the flow rate (kgh) and composition of the fresh feed and the overall and reactor heat
requirements (kW) for a production rate of 1500kgC2H4O? day.
 9.26. Ethylene oxide is produced by the catalytic oxidation of ethylene:

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