A balloon vendor at a street fair is using a tank of helium to fill her balloons. The tank has a volume of $199\mathrm{.}0$L and a pressure of $168\mathrm{.}0$ atm at $23\mathrm{.}0^$C$.$ After a while she notices that the valve has not been closed properly. The pressure had dropped to $158\mathrm{.}0$atm$.($The tank is $5$ till at $23\mathrm{.}0^$C $)$