Question: A complex [ML 6 ]Cl 2 was found to be octahedral, paramagnetic as well as having a temperature independent magnetic moment. We see in its

A complex [ML6]Cl2 was found to be octahedral, paramagnetic as well as having a temperature independent magnetic moment. We see in its UV-vis spectrum 3 spin-spin allowed d-d transitions. With v1= 980nm, v2 = 570nm, v3 obscured. The complex was reduced to form [ML6]Cl which had a magnetic moment of 1.92 BM.

Using appropriate reasoning decide what the identity of metal M is?

State is the magnetic moment of temperature dependent or independent?

how many d_d transitions would be allowed for [ML6]Cl2?

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