Question: A plot using the relationship: In([A]-[A]eg) = -( ki + k_1)t + In([A]. [A]eq) gave of a slope of 3 10-3 s/ for a cis-trans

A plot using the relationship: In([A]-[A]eg) = -( ki + k_1)t

A plot using the relationship: In([A]-[A]eg) = -( ki + k_1)t + In([A]. [A]eq) gave of a slope of 3 10-3 s/ for a cis-trans isomerisation. The equilibrium concentrations of the cis and trans isomers were 5 x 10-3 mol dm' and 1 x 10-2 mol dm 'respectively. -3 -3 Calculate: (i) The equilibrium constant, Keq. (ii) The rate constants k and k-1. What affect would an increase in reaction temperature have on the equilibrium constant? [8 marks]

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