Question: A small laboratory fixed bed 10.16 cm in diameter and 16 cm in length containing 600 g of activated carbon (C), has been used to

A small laboratory fixed bed 10.16 cm in diameter and 16 cm in length containing 600 g of activated carbon (C), has been used to adsorb n-butanol (B) from air containing 365 ppm of B. Measurements of the effluent concentration in terms of cout/cF as a function of time t are:

Cout/cF 0.0019 0.003 0.008 0.18 0.04 0.07 0.15 0.24 0.66 0.81 0.94 1.00
t, hr 5 5.5 6 6.5 7 7.5 8 8.5 10 11 12 13

Other pertinent data are: entering superficial gas velocity, us = 58 cm/s; T = 25C; P = 737 mm Hg; bed porosity, =0.456; average particle diameter, dp = 0.37cm; and butanol MW = 74.12 g/mol. A cylindrical vessel with an inside diameter of 2 ft and a height of 5 ft is available to conduct the adsorption on an industrial scale. The vessel can be packed with carbon to a 4 ft height. Plot the laboratory data and determine: (a) the mass velocity of the gas as it enters the bed in g gas/cm2 h, (b) the equilibrium loading of the carbon laboratory bed in g B/g C, and (c) the fraction of the laboratory bed utilied in the experiment if the breakthough time is taken at cout/cF = 0.05. For the industrial application calculate (d) the gas flow rate in kg/h for the same entering superficial velocity used in the laboratory experiment, (e) the fraction of the industrial bed that can be utilized, and (f) the estimated breakthrough time in h.

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