Question: a) Two radioactive nuclei decay by successive first order processes as follows: x y z The half-life for the first step is 22.5 days and

 a) Two radioactive nuclei decay by successive first order processes as

a) Two radioactive nuclei decay by successive first order processes as follows: x y z The half-life for the first step is 22.5 days and 33.0 days for the second step. (i) Calculate ki and k. Suppose Y is an isotope that is required for medical applications calculate the time that Y will be most abundant. [10 marks) b) The rate constant for the enzyme-catalysed decomposition of hydrogen peroxide, H2O2, increases by a factor of 3.8 when the temperature is increased from 298 K to 348 K. Determine the activation energy. [10 marks] c) The rates of the forward and reverse reaction were found to be 5.1 x 10 dm' mol's! and 1.9 x 10's respectively. Calculate the equilibrium constant for the reaction. [5 marks)

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