B. Draw the major product for each of the following reactions or reaction sequences. You needn't...
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B. Draw the major product for each of the following reactions or reaction sequences. You needn't bother to show side products or minor products. For chiral molecules that are racemic , you needn't draw both enantiomers. BE CAREFUL TO SHOW THE CORRECT ORIENTATION, AND THE CORRECT STEREOCHEMISTRY IN CASES WHERE STEREOCHEM IS FACTOR. (3 points each). H,SO, heat 8. OH Br NaOH 9. Br 10. HBr 11. HBr, peroxides 12. 1. HBr, peroxides 2. NaOCH3 13. H20, H* 14. 1. Hg(OAc), H20 15. 2. NaBH4 1. Hg(OAc), H20 2. NABH4 3. H2SO, 16. 1. ВН-THF 2. NaOH, H2O2 17. 1. ВН-THF 2. NaOH, H,O2 18. 1. Hg(OAc), CH;OH 2. NABH4 19. 1. HBr 2. NaOCH3 20. Br2 21. Br, H20 22. Br2 23. Bra H20 24. Cl, 25. Cl2 26. PhCO,H 27. PhCO,H 28. Ph CH;COH, H20 Ph 29. CH;CO,H, H2O 30. OsO, H,O2 Ph 31. Oso, H2O2 32. 1. O3 2. Me2s 33. 1. O3 2. Me,s 34. B. Draw the major product for each of the following reactions or reaction sequences. You needn't bother to show side products or minor products. For chiral molecules that are racemic , you needn't draw both enantiomers. BE CAREFUL TO SHOW THE CORRECT ORIENTATION, AND THE CORRECT STEREOCHEMISTRY IN CASES WHERE STEREOCHEM IS FACTOR. (3 points each). H,SO, heat 8. OH Br NaOH 9. Br 10. HBr 11. HBr, peroxides 12. 1. HBr, peroxides 2. NaOCH3 13. H20, H* 14. 1. Hg(OAc), H20 15. 2. NaBH4 1. Hg(OAc), H20 2. NABH4 3. H2SO, 16. 1. ВН-THF 2. NaOH, H2O2 17. 1. ВН-THF 2. NaOH, H,O2 18. 1. Hg(OAc), CH;OH 2. NABH4 19. 1. HBr 2. NaOCH3 20. Br2 21. Br, H20 22. Br2 23. Bra H20 24. Cl, 25. Cl2 26. PhCO,H 27. PhCO,H 28. Ph CH;COH, H20 Ph 29. CH;CO,H, H2O 30. OsO, H,O2 Ph 31. Oso, H2O2 32. 1. O3 2. Me2s 33. 1. O3 2. Me,s 34. B. Draw the major product for each of the following reactions or reaction sequences. You needn't bother to show side products or minor products. For chiral molecules that are racemic , you needn't draw both enantiomers. BE CAREFUL TO SHOW THE CORRECT ORIENTATION, AND THE CORRECT STEREOCHEMISTRY IN CASES WHERE STEREOCHEM IS FACTOR. (3 points each). H,SO, heat 8. OH Br NaOH 9. Br 10. HBr 11. HBr, peroxides 12. 1. HBr, peroxides 2. NaOCH3 13. H20, H* 14. 1. Hg(OAc), H20 15. 2. NaBH4 1. Hg(OAc), H20 2. NABH4 3. H2SO, 16. 1. ВН-THF 2. NaOH, H2O2 17. 1. ВН-THF 2. NaOH, H,O2 18. 1. Hg(OAc), CH;OH 2. NABH4 19. 1. HBr 2. NaOCH3 20. Br2 21. Br, H20 22. Br2 23. Bra H20 24. Cl, 25. Cl2 26. PhCO,H 27. PhCO,H 28. Ph CH;COH, H20 Ph 29. CH;CO,H, H2O 30. OsO, H,O2 Ph 31. Oso, H2O2 32. 1. O3 2. Me2s 33. 1. O3 2. Me,s 34. B. Draw the major product for each of the following reactions or reaction sequences. You needn't bother to show side products or minor products. For chiral molecules that are racemic , you needn't draw both enantiomers. BE CAREFUL TO SHOW THE CORRECT ORIENTATION, AND THE CORRECT STEREOCHEMISTRY IN CASES WHERE STEREOCHEM IS FACTOR. (3 points each). H,SO, heat 8. OH Br NaOH 9. Br 10. HBr 11. HBr, peroxides 12. 1. HBr, peroxides 2. NaOCH3 13. H20, H* 14. 1. Hg(OAc), H20 15. 2. NaBH4 1. Hg(OAc), H20 2. NABH4 3. H2SO, 16. 1. ВН-THF 2. NaOH, H2O2 17. 1. ВН-THF 2. NaOH, H,O2 18. 1. Hg(OAc), CH;OH 2. NABH4 19. 1. HBr 2. NaOCH3 20. Br2 21. Br, H20 22. Br2 23. Bra H20 24. Cl, 25. Cl2 26. PhCO,H 27. PhCO,H 28. Ph CH;COH, H20 Ph 29. CH;CO,H, H2O 30. OsO, H,O2 Ph 31. Oso, H2O2 32. 1. O3 2. Me2s 33. 1. O3 2. Me,s 34.
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