Question: ( c ) Derive an expression for the free energy of mixing of an ideal solution in terms of the mole fraction of the components,
c Derive an expression for the free energy of mixing of an ideal solution in terms of the mole fraction of the components, starting from the expression:
where is the molar Gibbs free energy, is the Gibbs free energy at standard pressure and and are the actual and standard pressures, respectively.
d Explain why two ideal solutions will tend to mix with one another over the whole composition range
i from the free energy of mixing;
ii in terms of the entropy and enthalpy of mixing ideal solutions.
e The enthalpy of mixing a regular solution is given by: where is some interaction parameter, and is the mole fraction of components A and Derive an expression for the free energy of mixing a regular solution. Determine the value to two significant figures of at which demixing will start to occur at
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