First consider the melting of gallium: Ga(s) Ga(l) a. Consider the following entropy data for gallium.
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Question:
First consider the melting of gallium:
Ga(s) → Ga(l)
a. Consider the following entropy data for gallium.
S°(liquid) | 59.25 J/mol*K |
S°(solid) | 40.83 J/mol*K |
Calculate the entropy change for the system. Show labelled work!
b. The ΔHofusion for gallium is +5.58 kJ/mol. Calculate the entropy change for the surroundings, assuming T=25 oC. Show labelled work!
c. Calculate the total entropy change, ΔSuniverse, for melting (assuming T=25 oC)
d. From a thermodynamics perspective then, based on your value for ΔSuniverse , why is gallium a solid at room temperature? What could be done to make melting more favorable? (to make the products more probable?) Explain your reasoning.
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