It is stated that little energy is involved in the distortion between square planar and tetra-...
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It is stated that little energy is involved in the distortion between square planar and tetra- hedral configurations. Use the angular overlap model to test the statement with Co2+ complexes in high and low spin states. Give a clear exposition of the calculation and discuss the results. The necessary tables are attached. [10] PERIODIEKE INDELING VAN DIE ELEMENTE IA (1) (18) 1 ПА IIIA IVA VA VIA VILA Не 1,01 (2) (13) (14) (15) (16) (17) | 4,00 4 13 atoomgetal simbool 5 6 7 9 10 Li Ве 6,94 9,01 Al B F Ne 27,0 10,8 12,0 14,0 16,0 19,0. 20,2 atoommassa 11 12 13 14 15 16 17 18 Na Mg IIIB IVB VB VIB VIIB EVIII- (9) (10) (8) IB IIB Al Si S CI Ar 23,0 24,3 (3) (4) (5) (6) (7) (11) (12) 27,0 28,1 31,0 32,1 35,45 39,9 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Са Sc Ti Cr 52,0 Mn 54,9 Fe 55,8 Co Ni Cu Zn Ga Ge 58,9 | 58,7 | 63,5 | 65,4 | 69,7 72,6| 74,9 | 79,0 79,9 | 83,8 50 As Se Br Kr 39,1 40,1 45,0 47,9 50,9 37 38 39 40 41 42 43 44 45 46 47 48 49 51 52 53 54 Rb Sr Y Zr Nb Мо Te Ru Rh Pd Ag Cd In Sn Sb Te I Хе 85,5 87,6 88,9 91,2 92,9 (98) 101,1 102,9 106,4 107,9 112,4 | 114,8|118,7 121,8 127,6 126,9 131,3 95,9 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ва La Hf Ta W Re Os Ir Pt Au 178,5 180,9 183,8 186,2 190,2 192,2 195,1 197,0 200,6| 204,4 207,2 209,0 (209) (210) (222) Hg TI Pb Bi Po At Rn 132,9 137,3 138,9 87 88 89 # 104 105 106 107 108 109 Fr Ac (223) 226,0 227,0 Ra Rf Db Sg Bh Hs Mt (261) (262)| (263)| (262) (265) (266) 58 59 60 61 62 63 64 65 66 67 68 69 70 71 * lantaniede Ce Pr Nd Pm Sm Eu Gd Но Er Tm Tb Dy Yb Lu 140,1 140,9 144,2 (145)| 150,4 152,0 157,3 158,9 162,5 164,9| 167,3 168,9 173,0 175,0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 23 aktiniede Th Pa U Np Pu Am Cm Bk Cf Es Fm | Md No Lr 232,0 231.0 238,0 237,0 (244) (234) (247)| (247) | (251) (252) | (257) (258) (258) (260) Skaleerfaktore / Scaling factors 4 12- M3 10 AB2 lineêr / linear: L 1; 6. AB3 trigonaal vlak / trigonal planar: L = 2; 11; 12. T-vorm / T form: L = 2; 4; 6 AB, tetrahedriesl / tetrahedral: L = 7; 8; 9; 10. vierkantigvlak / square planar: L= 2; 3; 4; 5 AB5 trigonaal bipiramidaal: L = 1; 2; 6; 11; 12. vierkantig piramidaal / square piramidal: L = 1; 2; 3; 4; 5. AB, okatahedries / octahedral: L = 1; 2; 3; 4; 5; 6. It is stated that little energy is involved in the distortion between square planar and tetra- hedral configurations. Use the angular overlap model to test the statement with Co2+ complexes in high and low spin states. Give a clear exposition of the calculation and discuss the results. The necessary tables are attached. [10] PERIODIEKE INDELING VAN DIE ELEMENTE IA (1) (18) 1 ПА IIIA IVA VA VIA VILA Не 1,01 (2) (13) (14) (15) (16) (17) | 4,00 4 13 atoomgetal simbool 5 6 7 9 10 Li Ве 6,94 9,01 Al B F Ne 27,0 10,8 12,0 14,0 16,0 19,0. 20,2 atoommassa 11 12 13 14 15 16 17 18 Na Mg IIIB IVB VB VIB VIIB EVIII- (9) (10) (8) IB IIB Al Si S CI Ar 23,0 24,3 (3) (4) (5) (6) (7) (11) (12) 27,0 28,1 31,0 32,1 35,45 39,9 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 K Са Sc Ti Cr 52,0 Mn 54,9 Fe 55,8 Co Ni Cu Zn Ga Ge 58,9 | 58,7 | 63,5 | 65,4 | 69,7 72,6| 74,9 | 79,0 79,9 | 83,8 50 As Se Br Kr 39,1 40,1 45,0 47,9 50,9 37 38 39 40 41 42 43 44 45 46 47 48 49 51 52 53 54 Rb Sr Y Zr Nb Мо Te Ru Rh Pd Ag Cd In Sn Sb Te I Хе 85,5 87,6 88,9 91,2 92,9 (98) 101,1 102,9 106,4 107,9 112,4 | 114,8|118,7 121,8 127,6 126,9 131,3 95,9 55 56 57 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 Cs Ва La Hf Ta W Re Os Ir Pt Au 178,5 180,9 183,8 186,2 190,2 192,2 195,1 197,0 200,6| 204,4 207,2 209,0 (209) (210) (222) Hg TI Pb Bi Po At Rn 132,9 137,3 138,9 87 88 89 # 104 105 106 107 108 109 Fr Ac (223) 226,0 227,0 Ra Rf Db Sg Bh Hs Mt (261) (262)| (263)| (262) (265) (266) 58 59 60 61 62 63 64 65 66 67 68 69 70 71 * lantaniede Ce Pr Nd Pm Sm Eu Gd Но Er Tm Tb Dy Yb Lu 140,1 140,9 144,2 (145)| 150,4 152,0 157,3 158,9 162,5 164,9| 167,3 168,9 173,0 175,0 90 91 92 93 94 95 96 97 98 99 100 101 102 103 23 aktiniede Th Pa U Np Pu Am Cm Bk Cf Es Fm | Md No Lr 232,0 231.0 238,0 237,0 (244) (234) (247)| (247) | (251) (252) | (257) (258) (258) (260) Skaleerfaktore / Scaling factors 4 12- M3 10 AB2 lineêr / linear: L 1; 6. AB3 trigonaal vlak / trigonal planar: L = 2; 11; 12. T-vorm / T form: L = 2; 4; 6 AB, tetrahedriesl / tetrahedral: L = 7; 8; 9; 10. vierkantigvlak / square planar: L= 2; 3; 4; 5 AB5 trigonaal bipiramidaal: L = 1; 2; 6; 11; 12. vierkantig piramidaal / square piramidal: L = 1; 2; 3; 4; 5. AB, okatahedries / octahedral: L = 1; 2; 3; 4; 5; 6.
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