Question: For the reaction 2 NO + O 2 = 2 NO 2 , which is of 2nd order in NO and first order in O

For the reaction 2 NO + O2 = 2 NO2, which is of 2nd order in NO and first order in O2, the reaction rate constant os kR= 2.8 x 106 L2/mol2s. a) Specify the basic kinetic equation for this case. b) Assume an excess of O2 and calculate the half time of creation for the following initial concentrations: CNO(0)=0.0001 mol/L ; CO2 (0) = 0.002 mol/L ; CNO2 (0) = 0 mol/L

c) The equilibrium constant for the reaction was found to be Keq = 6.4 x 105 L/mol. Calculate the corresponding backward reaction rate constant (with units!) and the equilibrium concentration of NO under the assumption that CNO,eqCNO (0).

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