Question: Polymerization reactions are often initiated by the decomposition of a di-halogen (like Br2), triggering its free radical. Derive the rate law for the overall
Polymerization reactions are often initiated by the decomposition of a di-halogen (like Br2), triggering its free radical. Derive the rate law for the overall consumption of Br2, specifically considering the following reaction mechanism: Br 2Br BrR+C R+ Br RBr + Br ->> 2R R Here, treat all free radicals as active centers, and invoke for them the steady-state approximation. Polymerization reactions are often initiated by the decomposition of a di-halogen (like Br2), triggering its free radical. Derive the rate law for the overall consumption of Br2, specifically considering the following reaction mechanism: Br 2Br BrR+C R+ Br RBr + Br ->> 2R R Here, treat all free radicals as active centers, and invoke for them the steady-state approximation.
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