Question: In statistic thermodynamics, we can use the partition function to calculate the thermody- namics properties of a system when the system is in thermodynamic equilibrium

 In statistic thermodynamics, we can use the partition function to calculate

In statistic thermodynamics, we can use the partition function to calculate the thermody- namics properties of a system when the system is in thermodynamic equilibrium . For a two level system with energy 1 = -0.01ev and 2 = 0.01 ev consists of No non-interacting particles in contact with a temperature reservoir, consider the following particle distributions: (a) A totally ordered distribution. All particles are in level 1: n1 = No and n2 = 0. Given that: F = U-TS S = klnQ Calculate the per particle Helmholtz energy F/No for this distribution (b) A totally disordered distribution. Particles are evenly distributed in two energy levels: n1 = n2 = No/2. Using Stirling's approximation, express the per particle Helmholtz energy F/No for this distribution as a function of temperature T (c) The equilibrium distribution, where the number of particles in each level and the Helmholtz energy of the system can be calculated from the partition function: No ni P exp KT F = -KT No In P Write down the single particle partition function of the system and use it to express the per particle Helmholtz energy F/No for this distribution as a function of temperature T (d) Use you answer in the first three parts, show that the equilibrium distribution will approach the totally ordered distribution at low temperature limit T - 0 and will approach the totally disordered distribution at high temperature limit Too

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