In Trans-1,2-dichlorocyclohexane, the diequatorial conformationof the Cl groups is less stable than the diaxial conformation, butin cis-1,3-dichlorocyclohexane,
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In Trans-1,2-dichlorocyclohexane, the diequatorial conformationof the Cl groups is less stable than the diaxial conformation, butin cis-1,3-dichlorocyclohexane, the diequatorial conformation ismorestable than the diaxial conformation, as we would typicallypredict. Draw the two chair conformations for the 1,2 and1,3-disubstituted cyclohexanes and explain why the trends areobserved using the dipole moments of the C- Cl bonds.
Related Book For
Organic Chemistry
ISBN: 978-1118133576
11th edition
Authors: Graham Solomons, Craig Fryhle, Scott Snyder
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