Isomerization of isobutane (A) to isobutene (B) on a catalyst uses the below surface reaction mechanism The rate determining step Reaction based on Langmuir Hinshellwood or Eley Rideal mechanism The net rate of reaction adsorption desorption expression for each step A K A (fast) k 1 k A B 2 (AB) (f...

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Isomerization of isobutane (A) to isobutene (B) on a catalyst uses the below surface reaction mechanism:

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Isomerization of isobutane (A) to isobutene (B) on a catalyst uses the below surface reaction mechanism:

The rate-determining step? Reaction based on Langmuir Hinshellwood or Eley Rideal mechanism?
The net rate of reaction/adsorption/desorption expression for each step?

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Fundamentals Of Momentum Heat And Mass Transfer

ISBN: 9781118947463

6th Edition

Authors: James Welty, Gregory L. Rorrer, David G. Foster

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Posted Date: Apr 04, 2024 09:41 AM

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Isomerization of isobutane (A) to isobutene (B) on a catalyst uses the below surface reaction mechanism:

Question:

A+ * K A* (fast) k_1 k A+B_2 (AB)* (fast) B+ k_3 * B* (fast) (AB)*+ B k4 C+D + (B)* (slow) A+ * K A* (fast) k_1 k A+B_2 (AB)* (fast) B+ k_3 * B* (fast) (AB)*+ B k4 C+D + (B)* (slow)

Expert Answer:

Fundamentals Of Momentum Heat And Mass Transfer

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A+ * K A* (fast) k_1 k A+B_2 (AB)* (fast) B+ k_3 * B* (fast) (AB)+ B k4 C+D + (B) (slow) A+ * K A* (fast) k_1 k A+B_2 (AB)* (fast) B+ k_3 * B* (fast) (AB)+ B k4 C+D + (B) (slow)