KIM$252$ Kimyasal Termodinamik

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Soru $1)$ a$)$ Maxwell ba$$nt$$lar$$n$$ kullanarak, hal denklemi $P=\frac{RT}{V-b}$ olarak verilen ger$$ek bir gaz i$$in "izotermal hacim de$$i$$imi i$$in entropi de$$i$$imi$"(\frac{\text{d}\text{e}\text{l}\text{S}}{\text{d}\text{e}\text{l}\text{V}}{)}_T$ ve "izotermal bas$$n$$ de$$i$$imi i$$in entropi de$$i$$imi$"(\frac{\text{d}\text{e}\text{l}\text{S}}{\text{d}\text{e}\text{l}\text{P}}{)}_T$ k$$smi diferansiyellerini veren ifadeleri t$$retiniz$.$

b$)$ Bu hal denklemine uyan $1$ mol CO gaz$$n$$n hacmi $100K\text{'}$de izotermal ko$$ullarda$,1L$ den $100$ L$\text{'}$e art$$r$$ld$$nda$,$ proses i$$in $S$ de$$i$$imini J$/$K cinsinden hesaplay$$n$$z; $)=(38\mathrm{.}72J{K}^{-1}$

c$)$ Bu hal denklemine uyan $1$ mol CO gaz$$n$$n bas$$nc$100K^{\text{'}}$ de izotermal ko$$ullarda$,5$ atm'den $50$ atm'e art$$r$$ld$$nda$,$ proses i$$in $S$ de$$i$$imini $\frac{J}{K}$ cinsinden hesaplay$$n$$z$.)$

Soru $2)$ Berthelot gaz$$n$$n s$$k$$t$$rma fakt$$r$$u $$ekilde veriliyor: