Question: please show more details (50 pts) Two Fe complexes, [Fe(bpy)2(CN)2] and [Fe(bpy)2(BCF)2], are shown here: iv a. (10 pts) Dete:mine the electron configuration and the

 please show more details (50 pts) Two Fe complexes, [Fe(bpy)2(CN)2] and

please show more details

(50 pts) Two Fe complexes, [Fe(bpy)2(CN)2] and [Fe(bpy)2(BCF)2], are shown here: iv a. (10 pts) Dete:mine the electron configuration and the valence electron count of Fe in both compounds. Are they diamagnetic or paramagnetic? b. (10pts) The CNB bond angle in [Fe(bpy)2(BCF)2] is about 171.8. Provide a reason why the CNB bond deviates from the expected linear arrangement. c. (20 pts )[Fe(oppy)2(CN)2] can be considered of a C2 point group; the character table of it is given below. Considering the CN stretching bands only and using group theory, perform a partial vibrational analysis and determine how many IR bands should be observed for the CN stretching. d. (10 pts) In thie IR spectrum of [Fe(bpy)2(CN)2],CN stretching modes are observed at 2070 and 2077cm1, while in [Fe(bpy)2(BCF)2], two bands at 2166 and 2181cmi are observed. Account for this cbservation

Step by Step Solution

There are 3 Steps involved in it

1 Expert Approved Answer
Step: 1 Unlock blur-text-image
Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock
Step: 3 Unlock

Students Have Also Explored These Related Chemistry Questions!