Question: Powell ( Trans . Inst. Chem. Eng. Lond., 1 3 , 1 7 5 ( 1 9 3 5 ) ; 1 8 , 3

Powell (Trans. Inst. Chem. Eng. Lond., 13,175(1935); 18,36(1940)] evaporated water from the outside of cylinders into an airstream flowing parallel to the axes of the cylinders. The air temperature was 25\deg C, and the total pressure standard atmospheric. The results are given by wl 23.17 x 10-%(ul)* Pu ~ Ba where w= water evaporated, g/cm?- s P,= partial pressure of water in airstream, mmHg Py = water-vapor pressure at surface temperature, mmHg u = velocity of airstream, cm/s ?= length of cylinder, cm (a) Transform the equation into the form_jp =(Re,), where Re, is a Reynolds number based on the cylinder length. (b) Calculate the rate of sublimation from a cylinder of napthalene 0.075 m diam by 0.60 m long (3 in diam by 24 in long) into a stream of pure carbon dioxide at a velocity of 6 m/s (20 ft/s) at 1 std atm, 100\deg C. The vapor pressure of naphthalene at the surface temperature may be taken as 1330 N/m?(10 mmHg) and the diffusivity in carbon dioxide as 5.15 & 107 m/s (0.0515 cm/s) at STP. Express the results as kilograms naphthalene evaporated per hour. Ans.: 0.386 kg/h.

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