Question: Q1 (a) Give Arrhenius' mathematical expression. You should also determine each term involved and explain the meaning and usefulness of this equation in reaction kinetics.

Q1 (a) Give Arrhenius' mathematical expression. You should also determine each term involved and explain the meaning and usefulness of this equation in reaction kinetics. (5 marks) (b) What is the half-life (t1/2) equation for a first-order reaction whose rate constant is k? Please show this explicitly through the first-order integrate rate law [8 marks) (c) Consider the following complete combustion reaction equation. CH + O + CO + HO (i) Balance this reaction equation [3 marks] (ii) Determine the reaction rate equation for both forward and backward reactions [3 marks] (iii) Determine the equilibrium constant Keq [3 marks] (d) If the rate constant of a 2nd order (unimolecular) reaction is 0.15 L mol s1, then calculate its half-life, (t1/2) for an initial concentration of reactant A, [A] = 0.1 M. [3 marks
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