Consider a system of distinguishable particles having only three energy levels separated by an energy which...
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Consider a system of distinguishable particles having only three energy levels separated by an energy which is equal to the value of KT at 30.0 K. The second energy level is doubly degenerate and the third is triply degenerate. (a) Calculate the molecular partition function at 300.0 K. [25 marks] (b) Calculate the electronic contribution to the molar internal energy at 300 K. [25 marks] (c) Calculate the electronic contribution to the molar heat capacity at 300 K. [25 marks] (d) Calculate the electronic contribution to the molar entropy at 300 K. Consider a system of distinguishable particles having only three energy levels separated by an energy which is equal to the value of KT at 30.0 K. The second energy level is doubly degenerate and the third is triply degenerate. (a) Calculate the molecular partition function at 300.0 K. [25 marks] (b) Calculate the electronic contribution to the molar internal energy at 300 K. [25 marks] (c) Calculate the electronic contribution to the molar heat capacity at 300 K. [25 marks] (d) Calculate the electronic contribution to the molar entropy at 300 K.
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