The chloronation of propene by HCl to 2-chloropropane in the gas phase HCl(g) + CH 3 CH=CH
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Question:
The chloronation of propene by HCl to 2-chloropropane in the gas phase
HCl(g) + CH3CH=CH2(g) CH3CHClCH3(g)
is assumed to have the following rate expression (in terms of partial pressures)
rate = kPmHClPnCH3CH=CH2
where m and n are integers. The reaction is thought to obey the following mechanism:
HCl + HCl (HCl)2K1-->
HCl + CH3CH=CH2complex K2-->
(HCl)2+ complex --> CH3CHClCH3+ 2HCl k3 (slow)
Verify that the mechanism is consistent with the reaction. Derive a rate expression from thismechanism and determine the values of m and n.
Related Book For
Elementary Principles of Chemical Processes
ISBN: 978-0471720638
3rd Edition
Authors: Richard M. Felder, Ronald W. Rousseau
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