Use the abbreviated trans-series below to predict, with explanation, the structure and stereochemistry of the final...

 

Transcribed Image Text:

Use the abbreviated trans-series below to predict, with explanation, the structure and stereochemistry of the final product formed by the successive reaction of the square planar complex [Pt(NH₂).] with one equivalent of chloride (CI) and then with one equivalent of a phosphine, PR3. If the order of ligand reagents were reversed would the product be of the same or opposite stereochemistry? Explain your answers throughout. NH; < Cl< Br<CN <I<PR; <H Volumes of activation (AV) for the exchange reaction (1) below are as shown [M(H₂O).] + H₂O* [M(H₂O),(H₂O*)] + H₂O (1) AV/cm³mol-¹ M V2+ Ni²+ - 4.1 +7.2 Discuss with explanation what this data reveals about the likely stoichiometric reaction mechanism for the two different reactions. Use the abbreviated trans-series below to predict, with explanation, the structure and stereochemistry of the final product formed by the successive reaction of the square planar complex [Pt(NH₂).] with one equivalent of chloride (CI) and then with one equivalent of a phosphine, PR3. If the order of ligand reagents were reversed would the product be of the same or opposite stereochemistry? Explain your answers throughout. NH; < Cl< Br<CN <I<PR; <H Volumes of activation (AV) for the exchange reaction (1) below are as shown [M(H₂O).] + H₂O* [M(H₂O),(H₂O*)] + H₂O (1) AV/cm³mol-¹ M V2+ Ni²+ - 4.1 +7.2 Discuss with explanation what this data reveals about the likely stoichiometric reaction mechanism for the two different reactions.

Answer rating: 100% (QA)

To predict the structure and stereochemistry of the final product formed by the successive reaction of the square planar complex PtNH342 with one equivalent ... View the full answer