The decomposition of nitramide, ONNH, in water has the chemical equation and rate law ONNH(aq) -...
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The decomposition of nitramide, O₂NNH₂, in water has the chemical equation and rate law O₂NNH₂(aq) - → N₂O(g) + H₂O(1) [O₂NNH₂] [H+] A proposed mechanism for this reaction is 1. O₂NNH₂ (aq) k = rate = k k₁ · O₂NNH¯(aq) + H+ (aq) (fast equilibrium) k_1 k₂ 2. O₂NNH(aq) 3. H+ (aq) + OH(aq) → H₂O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? N₂O(g) + OH¯(aq) (slow) Answer Bank The decomposition of nitramide, O₂NNH₂, in water has the chemical equation and rate law O₂NNH₂(aq) - → N₂O(g) + H₂O(1) [O₂NNH₂] [H+] A proposed mechanism for this reaction is 1. O₂NNH₂ (aq) k = rate = k k₁ · O₂NNH¯(aq) + H+ (aq) (fast equilibrium) k_1 k₂ 2. O₂NNH(aq) 3. H+ (aq) + OH(aq) → H₂O(1) (fast) What is the relationship between the observed value of k and the rate constants for the individual steps of the mechanism? N₂O(g) + OH¯(aq) (slow) Answer Bank
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