Question: The liquid phase reaction 2 A - > P was found to follow the rate law ( at 7 0 oC ) : - r

The liquid phase reaction
2A ->P
was found to follow the rate law (at 70 oC):
-r1=0.002 CA
2
(mol of A / L. s)
It is thought that the activation energy of this reaction is 176 J/mol (of A). The feed is
10%(molar fraction) of A in a solvent S, a solution with total concentration 44.2 mol/L;
the solvent is inert and the feed is at room temperature, 25 oC.
a. A CSTR of 1,000 L is available for the reaction. If the flow rate is such that
whatever the temperature of the reactor we ensure a conversion of 85% of A,
what will be the temperature of operation in adiabatic mode?
[60 Marks]
b. And what flow rate gives us the conversion of 85% at that temperature?
[40 Marks]
Data:
Specific heats:
A: 377 J/mol
S: 47 J/mol
P: 215 J/mol
Heats of formation at 25 oC:
A: 17 kJ/mol
P: -20 kJ/mol

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