the number one is solve with the table and the questions are a,b, c and d

and the other problem are number 6. I need to do a graph for temperature-composition with the table

For the binary furfural-water mixture at 1 atm pressure, the following values of composition in equilibrium liquid vapor pulsations in % in moles of furfural: 02 4 9.2 50 70 Y 0 8 9.2 9.2 9.2 9.5 TC 10098.1 97.9 97.9 97.9 98.7 80 90 92 94 96 100 11 19 32 64 81 100 100.6 | 109.5 122.5 146 154.8 161.7 A gaseous mixture consisting of 670 g of furfural and 54 g of water is cooled up to 138C. a) Calculate the number of moles of furfural in the condensate. b) At what maximum temperature will the entire system liquefy? c) If this liquid is redistilled in a fractionation column, what atmospheric pressure, what final products will be obtained hypothetically. 6.-For a series of temperatures, the vapor pressures of benzene and toluene are given in the following table Presin de Vapor (mmHg) T(F) Benceno Tolueno 116.2 760 180 811 314 185 882 345 190 957 378 195 1037 414 200 1123 452 205 1214 494 210 1310 538 215 1412 585 220 1520 635 225 1625 689 230 1756 747 231.1 760 Assuming that these compounds obey Raoult's Law and that the pressure total for the system is 1 atm, draw the temperature-composition for it