When calculating multicomponent distillation, why is it best to list the components in order of decreasing volatility?

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When calculating multicomponent distillation, why is it best to list the components in order of decreasing volatility? In such a list, do the two key components have to be adjacent?

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Separation Process Principles Chemical And Biochemical Principles

ISBN: 9780470481837

3rd Edition

Authors: By J. D. Seader, Ernest J. Henley, D. Keith Roper

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