NbN crystallizes with the NaCl type structure. Sketch out an MO diagram for octahedrally coordinated niobium and

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NbN crystallizes with the NaCl type structure. Sketch out an MO diagram for octahedrally coordinated niobium and use it to sketch a DOS plot for NbN. Indicate the relative area of the σ*, π*, and N 2p sets of bands, and mark the approximate position of the Fermi level in your DOS sketch. Would you expect NbN to be a metal or a semiconductor?

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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