Question: Show that for the Hamiltonian H = (h 2 /2m) 2 + U(r(vector)), an equivalent way of writing (1.9.9) is where E n (0) is

Show that for the Hamiltonian H = −(h̄2/2m)∇2 + U(r(vector)), an equivalent way of writing (1.9.9) isEn(k) = En(0) + dr * G7)[UG) Uo(7)]n() + ekR ( [[

where En(0) is the unperturbed atomic orbital energy and U0(r(vector)) is the potential energy function of a single atom. In other words, the band energy depends on the difference of the periodic potential and the single-atom potential.r *(7)[UG) Uo(F)]n( R) -R)). - n.n. (1.9.12)

En(k) = En(0) + dr * G7)[UG) Uo(7)]n() + ekR ( [[ r *(7)[UG) Uo(F)]n( R) -R)). - n.n. (1.9.12)

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