Question: Show that for the Hamiltonian H = (h 2 /2m) 2 + U(r(vector)), an equivalent way of writing (1.9.9) is where E n (0) is
Show that for the Hamiltonian H = −(h̄2/2m)∇2 + U(r(vector)), an equivalent way of writing (1.9.9) is![En(k) = En(0) + dr * G7)[UG) Uo(7)]n() + ekR ( [[](https://dsd5zvtm8ll6.cloudfront.net/si.question.images/images/question_images/1691/8/2/5/07464d733b22b6fb1691825067528.jpg)
where En(0) is the unperturbed atomic orbital energy and U0(r(vector)) is the potential energy function of a single atom. In other words, the band energy depends on the difference of the periodic potential and the single-atom potential.![]()

En(k) = En(0) + dr * G7)[UG) Uo(7)]n() + ekR ( [[ r *(7)[UG) Uo(F)]n( R) -R)). - n.n. (1.9.12)
Step by Step Solution
3.33 Rating (153 Votes )
There are 3 Steps involved in it
The Hamiltonian used in Eq 199 is given by 2m VUF ... View full answer
Get step-by-step solutions from verified subject matter experts
