Question: Consider a straight line connecting the point P 0, Z 1 to the critical point P PC, Z ZC on a Z versus P compressibility

Consider a straight line connecting the point P 0, Z 1 to the critical point P PC, Z ZC on a Z versus P compressibility diagram. This straight line will be tangent to one particular isotherm at low pressure. The experimentally determined value is about 0.8 TC. Determine what value of reduced temperature is predicted by an equation of state, using the van der Waals equation and the Redlich– Kwong equation. See also note for Problem 13.25.

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slope Zc1 PC0 But also equals From solution 1325 lim dz P0 ap T or lim P0 JP Pc lim Z1 P0 P0 V... View full answer

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