Question: Consider the DVD of Problem 14.49, except now the reacting polymer is blended uniformly with the polycarbonate to reduce manufacturing costs. Assume that a first-order

Consider the DVD of Problem 14.49, except now the reacting polymer is blended uniformly with the polycarbonate to reduce manufacturing costs. Assume that a first-order homogeneous chemical reaction takes place between the polymer and oxygen; the reaction rate is proportional to the oxygen molar concentration.

(a) Write the governing equation, boundary conditions, and initial condition for the oxygen molar concentration after the DVD is removed from the oxygen-proof pouch, for a DVD of thickness 2L.

Do not solve.

(b) The DVD will gradually become more opaque over time as the reaction proceeds. The ability to read the DVD will depend on how well the laser light can penetrate through the thickness of the DVD. Therefore, it is important to know the volume-averaged molar concentration of product, C prod, as a function of time. Write an expression for C prod in terms of the oxygen molar concentration, assuming that every mole of oxygen that reacts with the polymer results in p moles of product.

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