Consider the following sequence of steps to describe the high-temperature kinetics of NO reduction by CH4 on La2O3 and Sr = La2O3 in the absence
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Consider the following sequence of steps to describe the high-temperature kinetics of NO reduction by CH4 on La2O3 and Sr = La2O3 in the absence of O2:
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(a) Provide any necessary stoichiometric coefficient for each step to balance the overall reaction, i.e., no active centers are contained in the overall stoichiometry;
(b) Derive a kinetic rate expression from this sequence assuming NO* and CH2* are the only two significant surface species;
(c) Does the final rate expression have the capability of fitting the rate data reported in the paper by Vannice et al. [4], which gave reaction orders of 0.19–0.26 for CH4 and 0.73–0.98 for NO? Why?
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Write balanced sequence 1 4 NO 2 3 4 CH NO 5 HCHNO2 NO CONzH2ONa 3 6 2N N 2 KNO K NO N0 ... View full answer

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