Question: Derive Eq. (6.4c), making use of the Boltzmanns distribution. From Eq. (6.4c) obtain the expression for molar vibration heat capacity Cv vib of diatomic gas.

Derive Eq. (6.4c), making use of the Boltzmann’s distribution. From Eq. (6.4c) obtain the expression for molar vibration heat capacity Cv vib of diatomic gas. Calculate Cv vib for C12 gas at the temperature 300 K. The natural vibration frequency of these molecules is equal to 1.064 • 1014 s-1.

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By definition EeEkT exp EkT a 8 8 a ln e12 8 n e8v12k... View full answer

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